Pervaporation Membrane System

Pervaporation membrane separation technology is a sophisticated process that leverages the distinct thermodynamic and kinetic properties of organic solvents and water (or different components within solvents) within a dense membrane. This technology achieves separation by allowing water (or a specific component) to permeate through the membrane and subsequently vaporize on the other side, facilitating the separation process.

Unlike traditional distillation separation principles, pervaporation technology relies on membrane components. It is categorized into organic membranes, inorganic membranes, and hybrid membranes based on the type of membrane employed. The fundamental difference lies in the fact that pervaporation technology achieves separation based on the differential solubility and diffusion properties of components within the membrane, breaking free from the constraints of vapor-liquid equilibrium.

This innovative approach is particularly well-suited for the separation of liquid mixtures with either shared or close boiling points, such as ethanol/water or propanol/water. Pervaporation excels in scenarios where traditional distillation techniques face limitations. Additionally, it demonstrates exceptional efficacy in the removal of trace water from substances like acetone, tetrahydrofuran, t-butanol, and trimethyl borate. Furthermore, it offers economic and technical advantages in applications such as the recovery of trace organic compounds from industrial wastewater, coupling with other separation or reaction processes, and continuous removal of reaction by-products to enhance conversion rates.

Incorporating pervaporation membrane separation technology into your processes introduces a paradigm shift, offering notable economic and technical benefits. Explore the enhanced efficiency and versatility of separation with Greatwall Process and Control’s advanced membrane solutions.

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Additional information

Working Medium

Acetone, As per process demand, Butyl Alcohol, Ethanol, Ethyl acetate, Isopropyl Alcohol, Methyl Acetate, methylbenzene, Mixed Solvents, Tetrahydrofuran

Material heating method

Steam

Working Pressure

-0.1~1Pa

Production Material

Stainless Steel 304, Stainless Steel 316

Description

Pervaporation Membrane System

Technical Advantages:

Pervaporation technology stands out in various applications due to the unique principles of its separation process.

Let’s delve into the key advantages that make our Pervaporation Membrane System the choice for efficient and sustainable processes.

1. Energy Efficiency

Pervaporation technology requires significantly less latent heat of phase change, resulting in lower energy consumption. Operating at a mere 0.1 MPa of low-pressure steam or recycled steam from other systems sustains the normal functioning of the pervaporation membrane device.

This is a notable contrast to traditional setups that demand 0.3–0.4 MPa steam for regular operation.

In real-world applications, industrial ethanol production using pervaporation technology has demonstrated energy savings ranging from 50% to 75%, while the production of anhydrous isopropanol from 15% water content achieves a remarkable 65% energy reduction.

2 Environmental Friendliness

The simplicity of the pervaporation separation process eliminates the need for additional chemical additives, preventing additional environmental pollution.

For instance, when used for dehydrating organic solvents, the separated water, even though containing a small amount of organic solvent, can be easily recycled through a small-scale distillation process, minimizing waste and pollution.

In contrast, traditional salt-assisted extractive distillation techniques generate significant salt-containing residue during solvent recovery, posing challenges for environmentally friendly disposal.

Operational results reveal a reduction of 190 kg/ton COD emissions when utilizing pervaporation technology in the industrial ethanol production of anhydrous ethanol.

3. Avoid Product Contamination, Enhance Product Quality

In the production of pharmaceuticals and fine chemicals, the use of anhydrous-grade organic solvents is crucial from resource conservation, environmental, and cost perspectives.

Ensuring the recycling of solvents is vital, especially in preparing solvents with trace or minimal water content post-use.

Pervaporation membrane technology plays a pivotal role in this context by avoiding the introduction of third-party components during the separation of organic solvents and water.

This ensures the quality of the obtained anhydrous-grade organic solvents, guaranteeing the quality of pharmaceutical products.

4. Compact Footprint, High Resource Utilization

Pervaporation separation operations are unaffected by vapor-liquid equilibrium, simplifying distillation processes.

The resulting streamlined production process features a compact device structure, occupying minimal floor space for efficient operation.

Pervaporation technology excels in achieving economically effective dehydration at the ppm level, promoting increased product yield, reduced material consumption, and heightened resource utilization efficiency.

5. Flexible Operation, Easily Scaled for Industrial Use

The separation capacity of pervaporation membrane technology depends on the membrane’s inherent performance and surface area.

As such, it seamlessly accommodates both small-scale laboratory-level separations and large-scale industrial applications, with minimal variation in operational parameters.

Greatwall Process and Control provides complete solutions of pervaporation membranes as modular components facilitates adaptation to varying production requirements, ensuring operational flexibility and ease of industrial scaling.

Application Cases: Pervaporation Membrane Dehydration System

Our Pervaporation Membrane Dehydration System showcases remarkable efficiency across various applications.

Explore the distinctive advantages through these insightful case studies.

1. Ethanol Dehydration

Ethanol dehydration stands as the epitome of pervaporation technology applications.

Ethanol, a fundamental organic chemical and a crucial solvent, serves as an ideal high-octane fuel and additive for automotive use. Meeting the increasing environmental quality standards has made the development of alcohol-based fuels and ethanol additives a key pathway for enhancing automotive fuel.

With a vast market and substantial demand, ethanol ranks as the most extensively used alcohol globally.

Utilizing pervaporation membrane components for ethanol dehydration not only significantly reduces energy consumption but also avoids the necessity of introducing entrainers during the distillation process, showcasing clear advantages.

For instance, by feeding 80%-95% ethanol from the distillation column, our pervaporation membrane separation directly yields pure anhydrous ethanol with a purity exceeding 99.7%.

The separated water and a small amount of ethanol can be easily recycled through simple distillation, ensuring efficient recovery and reuse.

2. Acetone Solvent Dehydration

Although acetone and water do not have a azeotropic point, when the acetone content in the system reaches a certain range, a near-azeotropic system forms.

Traditional distillation methods struggle to separate acetone and water efficiently in such cases. Pervaporation membrane separation processes for acetone dehydration present a compelling case study.

In one project instance, with an acetone feed content of 88% and a target product content of 99.6%, a comparison between distillation and pervaporation processes highlighted the substantial reduction in energy consumption and the simplified operational and process aspects of pervaporation technology.

3. Coupled Application of Pervaporation and Distillation

In scenarios where water content is high, such as directly producing anhydrous ethanol from fermentation liquids with a water content of up to 90%, pure pervaporation may not be economically viable.

The coupling of traditional distillation and pervaporation processes emerges as the optimal solution. By integrating azeotropic distillation towers and pervaporation+atmospheric distillation processes, efficient and economically viable production of anhydrous ethanol is achieved.

The coupled process not only simplifies the operational flow but also surpasses 50% in energy savings, highlighting its significant advantages.

Explore the versatility and efficiency of our Pervaporation Membrane Dehydration System through these real-world applications, revolutionizing the landscape of solvent recovery and dehydration processes in various industries. Contact us for precise solution now.

Additional information

Working Medium

Acetone, As per process demand, Butyl Alcohol, Ethanol, Ethyl acetate, Isopropyl Alcohol, Methyl Acetate, methylbenzene, Mixed Solvents, Tetrahydrofuran

Material heating method

Steam

Working Pressure

-0.1~1Pa

Production Material

Stainless Steel 304, Stainless Steel 316

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